Precious metal catalysts replaced with polymer-supported iron –Highly efficient iron(0) nanoparticle-catalyzed hydrogenation in water in flow

Green Chemistry International

Graphical abstract: Highly efficient iron(0) nanoparticle-catalyzed hydrogenation in water in flow
Paper

Highly efficient iron(0) nanoparticle-catalyzed hydrogenation in water in flow

 
*
Corresponding authors
a
Centre in Green Chemistry and Catalysis, Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, Canada
b
Division of Complex Catalysis, Institute for Molecular Science, Okazaki, Japan

c
RIKEN Center for Sustainable Resource Science, 2-1 Hirowasa, Wako, Japan
Green Chem., 2013, Advance Article

DOI: 10.1039/C3GC40789F
Received 26 Apr 2013, Accepted 13 Jun 2013
First published online 27 Jun 2013

 
 
Highly efficient catalytic hydrogenations are achieved by using amphiphilic polymer-stabilized Fe(0) nanoparticle (Fe NP) catalysts in ethanol or water in a flow reactor.
Alkenes, alkynes, aromatic imines and aldehydes were hydrogenated nearly quantitatively…

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